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| 30.08.2010 | |||
| 22:00 | Atlético Madrid | 4-0 | Sporting Gijón |
| 29.08.2010 | |||
| 21:00 | Real Mallorca | 0-0 | Real Madrid |
| 19:00 | Racing Santander | 0-3 | FC Barcelona |
| 17:00 | Club Atlético Osasuna | 0-0 | UD Almería |
| 17:00 | Deportivo La Coruña | 0-0 | Real Zaragoza |
| 17:00 | Real CD Espanyol | 3-1 | Getafe CF |
| 17:00 | Real Sociedad | 1-0 | Villarreal CF |
| 28.08.2010 | |||
| 22:00 | Levante UD | 1-4 | Sevilla FC |
| 20:00 | Málaga CF | 1-3 | Valencia CF |
| 18:00 | Hércules CF | 0-1 | Athletic Bilbao |
| 12.09.2010 | ||||
| 17:00 | Athletic Bilbao | - | Atlético Madrid | |
| 17:00 | FC Barcelona | - | Hércules CF | |
| 17:00 | Getafe CF | - | Levante UD | |
| 17:00 | Real Madrid | - | Club Atlético Osasuna | |
| 17:00 | Real Zaragoza | - | Málaga CF | |
| 17:00 | Sevilla FC | - | Deportivo La Coruña | |
| 17:00 | Sporting Gijón | - | Real Mallorca | |
| 17:00 | UD Almería | - | Real Sociedad | |
| 17:00 | Valencia CF | - | Racing Santander | |
| 17:00 | Villarreal CF | - | Real CD Espanyol | |
| 19.09.2010 | ||||
| 17:00 | Atlético Madrid | - | FC Barcelona | |
| 17:00 | Deportivo La Coruña | - | Getafe CF | |
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