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| 06.11.2020 | Atlético Tucumán | 1-1 | Independiente | |
| 30.10.2020 | Independiente | 1-0 | Atlético Tucumán |
| 03.11.2020 | Bolívar | 3-0 | Audax Italiano | |
| 27.10.2020 | Audax Italiano | 2-1 | Bolívar |
| 06.11.2020 | Bahia/BA | 4-0 | FBC Melgar | |
| 30.10.2020 | FBC Melgar | 1-0 | Bahia/BA |
| 04.11.2020 | CD Huachipato | 1-1 | CA Fénix | |
| 28.10.2020 | CA Fénix | 3-1 | CD Huachipato |
| 04.11.2020 | São Paulo/SP | 4-3 | CA Lanús | |
| 28.10.2020 | CA Lanús | 3-2 | São Paulo/SP |
| 05.11.2020 | CA Peñarol | 1-1 | Vélez Sársfield | |
| 29.10.2020 | Vélez Sársfield | 0-0 | CA Peñarol |
| 05.11.2020 | Estudiantes FC (VEN) | 0-2 | Coquimbo Unido | |
| 29.10.2020 | Coquimbo Unido | 3-0 | Estudiantes FC (VEN) |
| 04.11.2020 | Defensa y Justicia | 1-1 | Sportivo Luqueño | |
| 28.10.2020 | Sportivo Luqueño | 1-2 | Defensa y Justicia |
| 05.11.2020 | Deportivo Cali | 1-2/p.5-4 | Millonarios | |
| 29.10.2020 | Millonarios | 1-2 | Deportivo Cali |
| 06.11.2020 | Junior Barranquilla | 0-0 | Plaza Colonia | |
| 30.10.2020 | Plaza Colonia | 0-1 | Junior Barranquilla |
| 04.11.2020 | River Plate (URU) | 3-1 | Atlético Nacional | |
| 28.10.2020 | Atlético Nacional | 1-1 | River Plate (URU) |
| 03.11.2020 | Liverpool (URU) | 1-2 | Sport Huancayo | |
| 27.10.2020 | Sport Huancayo | 1-1 | Liverpool (URU) |
| 04.11.2020 | Deportes Tolima | 1-1 | Unión La Calera | |
| 28.10.2020 | Unión La Calera | 0-0 | Deportes Tolima |
| 05.11.2020 | CS Emelec | 1-2 | Unión Santa Fe | |
| 29.10.2020 | Unión Santa Fe | 0-1 | CS Emelec |
| 06.11.2020 | Universidad Católica | 2-1 | Sol de América | |
| 29.10.2020 | Sol de América | 0-0 | Universidad Católica |
| 05.11.2020 | Caracas FC | 0-0 | Vasco da Gama/RJ | |
| 29.10.2020 | Vasco da Gama/RJ | 1-0 | Caracas FC |
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