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GMT 01:00
| 24.10.2020 | |||
| 21:00 | Atlético Madrid | 2-0 | Real Betis |
| 18:30 | CA Osasuna | 1-0 | Athletic Bilbao |
| 18:30 | Sevilla FC | 0-1 | SD Eibar |
| 16:00 | FC Barcelona | 1-3 | Real Madrid |
| 23.10.2020 | |||
| 21:00 | Elche CF | 2-1 | Valencia CF |
| 18.10.2020 | |||
| 21:00 | Real Betis | 0-3 | Real Sociedad |
| 18:30 | Deportivo Alavés | 0-2 | Elche CF |
| 18:30 | SD Huesca | 2-2 | Real Valladolid |
| 16:00 | Villarreal CF | 2-1 | Valencia CF |
| 14:00 | Athletic Bilbao | 2-0 | Levante UD |
| 12:00 | SD Eibar | 0-0 | CA Osasuna |
| 17.10.2020 | |||
| 21:00 | Getafe CF | 1-0 | FC Barcelona |
| 25.10.2020 | ||||
| 14:00 | Real Valladolid | - | Deportivo Alavés | |
| 16:00 | Cádiz CF | - | Villarreal CF | |
| 18:30 | Getafe CF | - | Granada CF | |
| 21:00 | Real Sociedad | - | SD Huesca | |
| 26.10.2020 | ||||
| 21:00 | Levante UD | - | Celta de Vigo | |
| 30.10.2020 | ||||
| 21:00 | SD Eibar | - | Cádiz CF | |
| 31.10.2020 | ||||
| 14:00 | Real Madrid | - | SD Huesca | |
| 16:00 | Athletic Bilbao | - | Sevilla FC | |
| 18:30 | CA Osasuna | - | Atlético Madrid | |
| 21:00 | Deportivo Alavés | - | FC Barcelona | |
| 01.11.2020 | ||||
| 14:00 | Real Betis | - | Elche CF | |
| 16:00 | Celta de Vigo | - | Real Sociedad | |
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