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Spain| 17.12.2022 | CF | SSC Napoli | 2-3 | Villarreal CF | |
| 25.02.2016 | EUL | SSC Napoli | 1-1 | Villarreal CF | |
| 18.02.2016 | EUL | Villarreal CF | 1-0 | SSC Napoli | |
| 07.12.2011 | CL | Villarreal CF | 0-2 | SSC Napoli | |
| 27.09.2011 | CL | SSC Napoli | 2-0 | Villarreal CF | |
| 24.02.2011 | EUL | Villarreal CF | 2-1 | SSC Napoli |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 4 | 2 | 0 | 11 | 4 | 7 |
| away | 6 | 1 | 4 | 1 | 6 | 6 | 0 |
| total | 6 | 4 | 2 | 0 | 9 | 2 | 7 |
| Napoli win | 28.57% | 2 |
| draw | 28.57% | 2 |
| Napoli lose | 42.86% | 3 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 3 | 1 | 10 | 6 | 4 |
| away | 6 | 4 | 0 | 2 | 7 | 7 | 0 |
| total | 6 | 3 | 2 | 1 | 7 | 7 | 0 |
| Villarreal win | 42.86% | 3 |
| draw | 28.57% | 2 |
| Villarreal lose | 28.57% | 2 |
| 27.04.2025 | D1 | SSC Napoli | 2-0 | Torino FC |  |
| 19.04.2025 | D1 | Monza | 0-1 | SSC Napoli | |
| 14.04.2025 | D1 | SSC Napoli | 3-0 | Empoli FC | |
| 07.04.2025 | D1 | Bologna FC | 1-1 | SSC Napoli |  |
| 30.03.2025 | D1 | SSC Napoli | 2-1 | AC Milan | |
| 16.03.2025 | D1 | Venezia FC | 0-0 | SSC Napoli | |
| 27.04.2025 | D1 | Villarreal CF | 1-0 | RCD Espanyol | |
| 23.04.2025 | D1 | Celta de Vigo | 3-0 | Villarreal CF |  |
| 20.04.2025 | D1 | Villarreal CF | 2-2 | Real Sociedad | |
| 13.04.2025 | D1 | Real Betis | 1-2 | Villarreal CF | |
| 06.04.2025 | D1 | Villarreal CF | 0-0 | Athletic Bilbao | |
| 30.03.2025 | D1 | Getafe CF | 1-2 | Villarreal CF | |
| over 2.5 | 48.65% | 18 |
| under 2.5 | 51.35% | 19 |
| over 2.5 | 62.86% | 22 |
| under 2.5 | 37.14% | 13 |
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