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Spain| 06.05.2021 | EUL | Arsenal FC | 0-0 | Villarreal CF | |
| 29.04.2021 | EUL | Villarreal CF | 2-1 | Arsenal FC | |
| 15.04.2009 | CL | Arsenal FC | 3-0 | Villarreal CF | |
| 07.04.2009 | CL | Villarreal CF | 1-1 | Arsenal FC | |
| 25.04.2006 | CL | Villarreal CF | 0-0 | Arsenal FC | |
| 19.04.2006 | CL | Arsenal FC | 1-0 | Villarreal CF |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 2 | 2 | 9 | 7 | 2 |
| away | 6 | 2 | 3 | 1 | 11 | 7 | 4 |
| total | 6 | 1 | 2 | 3 | 10 | 9 | 1 |
| Arsenal FC win | 33.33% | 2 |
| draw | 50.00% | 3 |
| Arsenal FC lose | 16.67% | 1 |
| GP | W | D | L | GF | GA | +/- | |
| home | 6 | 2 | 3 | 1 | 9 | 7 | 2 |
| away | 6 | 4 | 0 | 2 | 6 | 6 | 0 |
| total | 6 | 4 | 1 | 1 | 10 | 8 | 2 |
| Villarreal win | 16.67% | 1 |
| draw | 50.00% | 3 |
| Villarreal lose | 33.33% | 2 |
| 11.05.2025 | PR | Liverpool | 2-2 | Arsenal FC |  |
| 07.05.2025 | CL | Paris St. Germain | 2-1 | Arsenal FC |  |
| 03.05.2025 | PR | Arsenal FC | 1-2 | Bournemouth | |
| 29.04.2025 | CL | Arsenal FC | 0-1 | Paris St. Germain | |
| 23.04.2025 | PR | Arsenal FC | 2-2 | Crystal Palace | |
| 20.04.2025 | PR | Ipswich Town | 0-4 | Arsenal FC |  |
| 10.05.2025 | D1 | Girona FC | 0-1 | Villarreal CF | |
| 03.05.2025 | D1 | Villarreal CF | 4-2 | CA Osasuna | |
| 27.04.2025 | D1 | Villarreal CF | 1-0 | RCD Espanyol | |
| 23.04.2025 | D1 | Celta de Vigo | 3-0 | Villarreal CF | |
| 20.04.2025 | D1 | Villarreal CF | 2-2 | Real Sociedad | |
| 13.04.2025 | D1 | Real Betis | 1-2 | Villarreal CF | |
| over 2.5 | 50.00% | 28 |
| under 2.5 | 50.00% | 28 |
| over 2.5 | 62.16% | 23 |
| under 2.5 | 37.84% | 14 |
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